During. Not sure if it makes a difference in the final product, but I want to make sure it tastes good before I toss it in with the rest of the chili.

Kenji has convinced me that it’s not worth trying to get a good sear on ground meat in chili and bolognese. In his recipes the ground beef is cooked with the chili paste, garlic, and onions (or with other stuff in the ragu). The lost maillard flavors can be recovered with soy sauce, fish sauce, marmite, and MSG.

So to answer your question, during. Kind of, since it gets flavored by the other stuff.

I think the only wrong answer is before, because that will give the meat a sausage consistency. I don’t want rubbery beef in my chili.

Also well done on asking a chili question that doesn’t start a war about beans.

Right before it goes into the pan/pot. You want to at least use salt at this point to keep moisture in the meat while cooking and allowing it to brown better before you start tossing in everything else.

Try stewing steak instead of ground beef… I won’t go back

I don’t use ground meat for chili, typically I will use a braising cut. For that, I salt it, and let it air dry for a bit, then sear it. When it’s nicely browned, I’ll pull the meat out, throw in onions to deglaze the pan, then garlic, any spices that could use a toasting (like cumin), and some tomato paste.

Finally I pour in my chile puree, which in my opinion is a non-negotiable part of what make chili, chili. That’s just a combo of a few different types of dried chiles that I’ve toasted, soaked in liquid like chicken stock, blended, and passed through a sieve. Then I slice up the meat, and put it back in.

If I were to use ground beef, I would basically just do the same thing, but I’d skip the salting part and just do it all after I add the liquid. It’s hard to get good color on ground beef if you have a big hunk of it, especially if any moisture is pulled out of it. Sometimes if I need to brown a bunch of ground beef, I’ll do it in batches, basically cooking each chunk like a separate “burger”. If I’m lazy, I’ll do however much can fit in a single layer well spaced, then just toss the rest in after. I’d rather have half of the meat well browned than all of it “grey”.

My chili powder (Alton Brown recipe and other stuff) goes into the pan with a little hot fat just before I brown the meat. This way it can borrow a truck from curry and fry the spices a minute before they come in contact with the meat.

Before: cumin, garlic, paprika. After: everything else, including salt.

Those three when browned are delicious, the others either burn easily (like oregano) or are liquid (like my pepper sauce).